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Recently, Chen Qing’an, researcher of the Biomimetic Catalytic Synthesis Innovation Special Zone Research Group of the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, has made progress in the redox divergent coupling of ketones and terpene alcohols catalyzed by palladium.
With the help of oxidoreductases, organisms can produce a series of important metabolites in different redox states for life activities.
Chen Qingan's team is committed to the development of different catalytic systems to realize the resource utilization of enols, alkynes and alkenes.
The related research results are titled Pd-Catalyzed Redox Divergent Coupling of Ketones with Terpenols and published on ACS Catalysis.
A new strategy for the regulation of different redox states of coupling products by adjusting the redox ability of the Pd catalytic center by changing solvents and additives