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Catalytic reactions based on metal carbene, especially cross-coupling reactions, have developed rapidly in recent years.
Figure 1.
Another important development of Wang Jianbo's group in the research of carbene coupling is the asymmetric insertion reaction of carbene to carbon-silicon bond catalyzed by palladium
Figure 2.
In addition to its application in organic synthesis, the migration and insertion of palladium carbene is also a key step in the polymerization of carbene C1
Figure 3.
The kinetic study showed that in the initial stage of the polymerization reaction, the molecular weight increased to the maximum value, and with the increase of the conversion rate, it has been maintained near the maximum value, indicating that the reaction has the characteristics of slow initiation and rapid growth
Figure 4.
The first authors of the above papers are Ping Yifan, a 2016 PhD student in the School of Chemistry and Molecular Engineering, Peking University, Huo Jingfeng, a Boya postdoctoral fellow, and Yao Xingqi, a 2016 PhD student
Original link:
https://pubs.
https://pubs.
https://pubs.