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In the actual article, four new pyrithrotic derivatives (expressed as PT1, PT2, PT3 and PT4) are specially designed by molecular models, which have good light absorption properties at 405 nm through molecular modeling.
Synthesizes the most interesting structures that show strong purple/blue light absorption and high potential photochemical reactive properties for detailed studies of light triggers/photosensitive agents in the presence of iodinesalt, which is used for free-based photoreceptual polymerization of (methyl) acrylics and cation polymerization of cyclooxides. Near ultraviolet or visible light
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Excellent aggregation rate and high conversion rate for final reaction functions
It is worth noting that the two proposed structures in this computer design (PT3 and PT4) were never synthesized prior to this work and are therefore specifically designed for this work. A three-group dlight-triggering system based on PT/iodine/amine (N-phenyl glycine or 4-methylene methamphetamine) for free-form polymerization of acrylic has also been developed. Excellent aggregation rate and high conversion rate of final reaction function are obtained.
using different techniques to provide images of photochemical processes: real-time Fourier transform infrared spectra, ultraviolet visible spectra, fluorescence spectra, and cyclical vian methods. Finally, the high performance of the molybon derivatives is also shown in 3D printing experiments and in photofibre synthesis using fiberglass (thicker samples; using LED s 395 nm conveyor belt).
the study was published in the 19th issue of Polymer Chemistry in 2020.
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