Anhui University of Science and Technology Yin Chengjie/Professor Pan Chengling "ACS AMI": In metal organic framework materials (MOF)...

Water resistance can be charged electrically zinc from the sub- electric cell ( the Z the I B S ) due to its safety full of high , capacity amount of large ( Li theory capacity amount is .
8 2 0 m A H/ G ) and lead from a person who is very large Xing interest zinc of a high abundance of , low to the presentAnd low oxygen of further primary electrical bit ( with standard quasi- hydrogen electric pole phase ratio is 0 .
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7 .
6 V)
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Head before , the Z the I B S of the primary to the barrier obstruction of a is the cathode electrode material feed is has limited option selection

Recent period , Ann logo management engineering large school of Science Engineering process Science Institute YIN into Jie Bo Shi and material feed Science Institute Pan into Ridge EDUCATION Shou in gold metal with a machine frame carrier material material ( M O F.

) Water -based zinc from the sub- reservoir deposit side plane take obtain new the intake development , to provideHigh gold metal with a machine frame frame member material is electrically oriented learning reservoir zinc living property , the class title set design basis braking apparatus of a Species with bit no unsaturated and gold metal with a machine frame rack water -based zinc from sub positive electrode sheet material , phase off to result in marked title as " COo r d i n a t e l y U n s a t u r a t e d M a n g a n e s e - B a s e d M e t a l – O r g a n i c F r a m e w o r k s a sa H i g h - P e r f o r m a n c e C a t h o d e f o r A q u e o u s Z i n c - I o n B a t t e r i e S" fat table in A C S A P P l i e d M a t e r i a l s & I n t e r f a c e s

FIG .

1 .
( A ) M n- - H .

FIG 2 .

M O F.
S powder at the end of C , O , and M n- membered element of H R & lt T E M FIGS image and E D S membered element mapping exit : ( A ) M n- - H .

FIG .

3 .
M n- - H .

FIG 4 .

Engaged into the sample product of F.
T the I R & lt light spectrum : ( A ) M n- - H .

FIG .

5 .
( A ) having has 2 M the Z n- ( C F.

FIG .

6 .
( A , B ) circulating loop M n- - H .

FIG.
7 .
Is not the same charge and discharge electric stage segment circulation loop power electrode of the non- original bit X- R & lt D in FIG spectrum
.

FIG .
8 .
( A ) M n- - H .
3 B T C - M O F.
- .
4 in not different scan described speed ratio at the C V curve line , ( B ) C V curve line of the anode electrode peaks and the cathode electrode peak of l O G ( peak value power flow ) and l O G ( scan described speed ratio ) is off line in FIG , ( C ) 0 .
.
1 m V S ^{? .
1} when the electrical capacitance tribute offer ( orange color portion minutes ) and spread dispersion Gong literature ( purple color portion minutes ) , to and ( D ) is not the same scan described rate of the electrical Volume ratio Gong contribution of the column -like FIG
.

The total of , the present paper the first to put out of a Species coordination tune is not saturated and policy strategy to increase strength the Z the I B S of M n- - H .
3 B T C - M O F.
- .
4 cathode electrode of times the rate and circulation loop of Can
.
With M n - H 3 B T C- M O F.
- 2 and M n- - H .
3 B T C - M O F.
- .
6 phase ratio , which is electrically very suitable when the not saturated and with bits of as the Z n- ² from the sub- transmission transmission provide for a more smaller of space between bit hindered and the more lower the electrical sub- transmissionTransmission resistance force
.
Due to this , increased intensity of mass quantity and an electrical charge transfer transmission Laid properties in and of zinc from the sub- memory storage of the appropriate degree of affinity and force conduction induced significantly significant increase in strength of this intrinsic live property and electrical of learning dynamic force Science
.
Machine rationale research study table Ming , M n-- H .
3 B T C - M O F.
- .
4 of zinc storage memory can be divided to two th step step : ( I ) M O F.
S in the M n- ² is the Z n- ² set to change , and ( I I ) M n- ² oxygen of is M n- O ₂ and formed into a Zn- M n- _.
3 O _.
7 ·.
3H ₂ O of engagement thereof
.
This species based on MOF.
The electric pole in .
100mAG ^{? .
1} the device has .
1.
3.
8mAHG ^{? .
1} is preferably different capacity amount , and and at .
3000mA G ^{? .
1} at cycle loop .
1 .
5 0 0 times after having there .
9 .
3 .
.
5 % of ultra- high capacity amount security hold rate
.
Total 's to say , M n- - H .
3 B T C - M O F.
- .
4 of the Z n- ² from the sub- memory storage properties can exceed over the mostNear reported tract of large multi- number M O F negative pole
.
This entry work as to explore cable coordination transfer is not saturated and M O F.
Sheet material to a solid current high property can be the Z the I B S provide for a new way path
.

Phase off link connection

C h e n g j i e Y i n * , C h e n g l i n g P a n * , X i a o b o L i a o , Y u s o n g P a n * , a n d L i a n g Y u a n * .
C o o r d i n a t e l y U n s a t u r a t e d M a n g a n e s e - B a s e d M e t a l – O r g a n i c F r a m e w o r k s a s a H i g h - P e r f o r m a n c e C a t h o d e f o r A q u e o u s Z i n c - I o n B a t t e r i e s .
A C S A p p l .
M a t e r .
I n t e r f a c e s

H T T P S : / / D O I .
O R & lt G / .
1 0 .
.
1 0 2 .
1 / A C S A m I .
.
1 C .
1 0 0 .
6 .
3